If you speak English, the Duolingo i Phone app offers 20 languages for you to learn.
They are Danish, Dutch, Esperanto, French, German, Hebrew, Hungarian, Irish, Italian, Japanese (the newest language added), Norwegian, Polish, Portuguese, Russian, Spanish, Swedish, Turkish, Ukrainian, Vietnamese, and Welsh.
If you're studying a language, no doubt you've heard of Duolingo, which is the best free program you'll find.
The fantastic web app comes with equally free mobile apps that let you practice your language on the go, and the i Phone app is, like the website, the best free language-learning app you can find.
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As a bonus, you do not even need to register to try them :-). You can access these chat rooms from your regular mobile-phone itself! You however need to register in order to post your comment.
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Rock Chat is the best place to find friendship online, indulge in dating on your mobile phone, have a free chat in chatrooms and rock with friends from around the world on your internet enabled device.
At the time of this writing, on the full Duolingo website, Hebrew, Hungarian, and Vietnamese were listed as still being in beta.
Note that these are the languages available in the the i OS version; you might see a few differences in what's available on Android and the website.